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ZPA – Zeta Potential Analyzer

The Zeta Potential Analyzer ZPA 20 uses the patented bidirectional oscillating streaming potential analysis to measure the zeta potential of fibers, powders and plate shaped solid materials. Applications that depend on the adhesion between solids, the adsorption and chemical reaction of ions/molecules, surfactants, polymers etc. can all benefit from investigating the zeta potential and its changes depending on the pH value.

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Electrical double layer and zeta potential

Ions inside a polar liquid are surrounded by polarized solvent molecules that are loosely bound to the ion. In the case of water this assembly is called a hydrated ion.

Most surfaces develop a surface charge when they come into contact with liquids. The surface charge can be caused by different processes like ion adsorption as well as protonation or dissociation of functional surface groups. The surface charge generates an electric field, which attracts counterions in the liquid towards the surface.

In front of the surface the so called electrical double layer forms which consists of an immobile and a diffuse layer. The immobile layer can be further divided into the inner Helmholtz plane (IHP) and the outer Helmholtz plane (OHP). The inner Helmholtz plane is defined by specifically adsorbed ions that are tightly bound to the surface at a short distance. These ions are partly dehydrated.

Following this plane of specifically adsorbed ions are counterions which are non-specifically adsorbed and are fully hydrated. This defines the outer Helmholtz plane. Following the immobile layer is the mobile diffuse layer which contains hydrated coions and counterions. The number density of the ions is influenced by the surface charge and hence the density decreases with distance to the surface. In addition to the electrostatic potential of the immobile layer the ions in the diffuse layer experience thermal Brownian motion. Since the ions in the diffuse layer are not bound to the surface, they can be sheared off by a liquid flow that is for example caused by a pressure difference.

Electrical potential in front of a surface according to the GCSG model

The electrical potential across the electric double layer can also be divided into two parts. Across the immobile layer the absolute value of the potential is assumed to decrease linearly. Inside the diffuse layer the electrical potential is defined by a Boltzmann distribution.

The potential inside the immobile layer is experimentally inaccessible but is also not relevant for practical applications. The potential at the transition between immobile and diffuse layer on the other hand can be measured.

By moving the liquid and the surface relative to each other the ions inside the diffuse layer can be sheared of. The electrical potential at this shear plane is called zeta potential (ζ potential).

The ζ potential directly influences the stability of colloidal suspensions and gives indications on the adhesion between solids. Furthermore, the ζ potential can be used to monitor the adsorption and chemical reaction of ions/molecules, surfactants, polymers etc. with the solid surface.

Fields of application

How zeta potential measurements can help to clean your clothes

By determining the ζ potential the behavior of the interface between solid and liquid can be characterized. Additional parameters like the isoelectric point and the adsorption kinetic of the solid can be derived from ζ potential analysis. Hence, applicative questions from many fields can be answered. These applications include among others:

Food technology

  • membrane filtration: characterization and quality control of membranes for selective fractionation.
  • antimicrobial surfaces: optimization of surfaces used in food packaging and food processing to prevent the adsorption of microorganisms.
  • particle interaction in food formulations: investigation of stability and interaction depending on the pH value.

Biocompatible material

  • dental implants: investigation of adsorption of proteins on the implants surface in order to characterize the formation of biofilms.
  • tissue engineering: modification of polymer surfaces to improve cytoadhering.
  • dialysis membranes: modification of the filtration fibers to increase biocompatibility.
  • contact lenses: reduction of biofilms and adhesion of bacteria on the lens surface as well as investigation of long-term stability and biocompatibility.

Filtration membranes

  • virus filtration: modification of the surface charge of filter media in order to filter water contaminated with viruses.
  • seawater salt removal: investigation of interaction between seawater components and filtration membranes by time dependent ζ potential analysis.
  • membrane fouling: fouling processes can be identified by time dependent ζ potential analysis in order to increase the membrane efficiency.

Textile industry

Worlds first bidirectional oscillating streaming potential analysis

Stamp labeled patented technology

DataPhysics Instruments patented a measuring technique that uses an oscillatory flow of electrolyte solution through or along the sample. The streaming potential and the currently applied pressure are measured simultaneously together with the temperature, conductivity and pH value of the electrolyte solution. Through the wide range of applicable flow frequencies and amplitudes a fast and precise measurement is possible. The method has the following advantages:

  • Oscillation with frequencies of up to 0.5 Hz allows 60 pressure ramps to be recorded in 60 s, leading to a higher statistical quality
  • Oscillation flow of the electrolyte solution avoids polarization effect at the measurement electrodes
  • Total surface in contact with the electrolyte is small (no tubing, extra vessels) ensuring an easy and complete cleaning to avoid cross-contaminations
  • Open architecture enables fast mixing and data acquisition with time resolved ζ potential measurements for studying of adsorption and surface modification kinetics
  • Open architecture allows customization through attachments such as spectrometers for simultaneous detection of concentration changes and streaming potential
  • Measuring cells can be loaded and prepared outside the system to allow for parallel measurement and sample preparation
  • Controlling the packing densities of fiber and powder samples using a torque wrench allows for unrivalled reproducibility in sample preparation
  • Transparent measuring cell allows to easily detect sources of errors such as air bubbles
  • Highly sensitive measurements due to large electrode surfaces to detect even the slightest changes of surface properties

Schematic measuring setup of the Zeta Potential Analyzer ZPA 20

ZPA 20

The Zeta Potential Analyzer ZPA 20 is a compact measuring instruments that utilizes the patented bidirectional oscillating streaming potential method. It is designed to measure the zeta potential of various macroscopic solid samples with highest accuracy and within shortest time.

The ZPA 20 uses removable measuring cells for various types of materials. Hence, plate shaped samples as well as fibers and powders can be easily prepared and placed into the system. A consistent packing density of powders and fibers can be ensured using a torque wrench. The ZPA 20 features high precision measuring probes for voltage, current, conductivity, pH value, pressure and temperature.

With its powerful stepping motor the ZPA 20 can create an oscillating flow of the electrolyte with frequencies of up to 0.5 Hz and hence, the zeta potential can be measured in under a minute with a high statistical quality and across a multitude of applied pressures.

Concentration dependent measurements can be done using the optional liquid dosing unit LDU 25. For example, the isoelectric point can be determined automatically by adding basic or acidic solutions to the electrolyte and hence, changing the pH value.

Main features

Software

The ZPA 20 is controlled via the ZPASoftware. Learn more about the Software for the ZPA 20.

Accessories

The ZPA 20 can be used with different measuring cells for various materials. With the liquid dosing unit LDU 25 concentrations in the electrolyte can be changed automatically like e.g. the pH value. Learn more about the available accessories.

ZPA brochurefile_download

Zeta Potential Analyzer ZPA 20